The club from the capital, who qualified for this round by finishing 13th in the league-phase with 11 points from 6 matches, will face the Belarusians, who were among the winners of the national-champions path and who knocked out FC Ordabasy Shymkent (1–1, 2–0), PFC Ludogorets Razgrad (0–1, 2–0) and FC Dinamo Tbilisi (0–2, 2–0, 4–2 on penalties) to reach the Round of 32. The tie will be played as a single match on Tuesday 3 or Wednesday 4 February 2026.
Chelsea FC (ENG) - PSV Eindhoven (NED)
SL Benfica (POR) - SK Slavia Prague (CZE)
Club Bruges KV (BEL) - AS Monaco (FRA)
Real Madrid CF (ESP) - Olympique de Marseille (FRA)
Villarreal CF (ESP) - Bayer 04 Leverkusen (GER)
Athletic Club (ESP) - Eintracht Frankfurt (GER)
FC Dynamo Kiev (UKR) - Atlético de Madrid (ESP)
Maccabi Haïfa FC (ISR) - FC Barcelone (ESP)
Real Betis Balompié (ESP) - Tottenham Hotspur (ENG)
HJK Helsinki (FIN) - Manchester City (ENG)
AZ Alkmaar (NED) - Borussia Dortmund (GER)
Puskas Akadémia FC (HUN) - Sporting Clube de Portugal (POR)
FC Dinamo-Minsk (BLR) - Paris Saint-Germain (FRA)
1. FC Cologne (GER) - FC Internazionale Milan (ITA)
Legia Varsovie (POL) - AFC Ajax (NED)
MSK Zilina (SLQ) - Liverpool FC (ENG)